At least 17 people were killed in the "massive attack" overnight on Ukraine's capital, as mayor Vitali Klitschko warns hot water supply has been disrupted.
The brothers have had a fractured relationship for a number of years.
Alessandro Rapinese issues the prohibition for the historic city centre after an encounter with a cyclist last month.
Gaël Mocaër and Sebastian Perez Pezzani's detention is "unjustified and disproportionate", Reporters Without Borders says.
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